DOI码：10.1021/acs.jpcc.9b00395
所属单位：University of Science and Technology Beijing
发表刊物：The Journal of Physical Chemistry C
摘要：Herein, we provide a direct explanation for the reverse garnet effect based on polyhedron competition. On multisite substitution, the deformation of the dodecahedron which will accommodate Ce3+ meets suppression from a neighboring octahedron and tetrahedron. This makes the dodecahedral deformation nonisotropic. Further, it is found that the lowest 5d state of Ce3+ in garnet is closely related to th
合写作者：Quan Lin Liu
第一作者：Zhen Song
论文类型：期刊论文
文献类型：期刊论文
卷号：123
期号：14
页面范围：8656-8662
ISSN号：1932-7447, 1932-7455
是否译文：否
发表时间：2019-04-11