Effects of Neighboring Polyhedron Competition on the 5d Level of Ce3+ in Lanthanide Garnets

Date:2026-10-01 clicks:

DOI number:10.1021/acs.jpcc.9b00395

Affiliation of Author(s):University of Science and Technology Beijing

Journal:The Journal of Physical Chemistry C

Abstract:Herein, we provide a direct explanation for the reverse garnet effect based on polyhedron competition. On multisite substitution, the deformation of the dodecahedron which will accommodate Ce3+ meets suppression from a neighboring octahedron and tetrahedron. This makes the dodecahedral deformation nonisotropic. Further, it is found that the lowest 5d state of Ce3+ in garnet is closely related to th

Co-author:Quan Lin Liu

First Author:Zhen Song

Indexed by:Journal paper

Document Type:期刊论文

Volume:123

Issue:14

Page Number:8656-8662

ISSN No.:1932-7447, 1932-7455

Translation or Not:no

Date of Publication:2019-04-11

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